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Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/11453

Title: The electrochemistry of some novel organic conductors and their precursors
Authors: Martin Grossel
D.B. Hibbert
A.E. HamedElniel
Keywords: Tetrathiafulvalene ,
Oxonol Dyes
Cyclic Voltammetry.
Issue Date: 1989
Abstract: Conducting salts of tetrathiafulvalene (TTF) and a series of oxonol dyes have been prepared electrochemically by the in situ oxidation of TTF in the presence of the anion of the dye. The salt having the greatest conductivity (0.1 Sm−1) is a TTF-N-ethyl hydroxypyridone trimethine oxonol salt. A cyclic voltammetric study of the salts and precursors, electron spin resonnce and photoelectron spectra and the pH dependence of the rest potential are reported. On heating above 150°C the conductivity of the complex and the esr signal decayed, although this is a lower temperature than that at which the complex decomposes (256°C).
URI: http://hdl.handle.net/123456789/11453
Appears in Collections:College of Teaching

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