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| Title: | Synthesis and Structural Characterization of a Halide-Free Rhombohedral Silver-Alkynyl Cage Complex [Ag14(C2tBu)12][BF4]2 |
| Authors: | M. Abu-Salah, Omar.
H, Mohammed.
Ja’far
Al-Ohaly, Abdel Razzak.
A. Al-Farhan, Khalid.
S. Al-Enzi, Hamda.
V. Dolomanov, Oleg.
A. K. Howard, Judith. |
| Keywords: | Silver; Clusters; Silver alkynyls; Alkynyl cluster; Cationic silver complex; Silver cage complex; Rhombohedral silver cage |
| Issue Date: | 2006 |
| Publisher: | European Journal of Inorganic Chemistry |
| Citation: | European Journal of Inorganic Chemistry |
| Abstract: | The novel cationic complex [Ag14(C2tBu)12]2+ has been synthesized by four reactions: reaction of [Ag(C2tBu)]n and AgBF4 in acetone in a 6:1 mole ratio, that of HC≡CtBu and AgBF4 in water in the absence of a base, treatment of [AgC2tBu]n with HBF4 in acetone or that of {[Ag3(C2tBu)2][BF4]}n with [Ag(C2tBu)]n in a 1:4 mole ratio. Single-crystal X-ray studies showed it to be a hexacapped cube of silver(I) atoms, with twelve η1, μ3-C2tBu ligands. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) |
| URI: | http://hdl.handle.net/123456789/18428 |
| ISSN: | DOI: 10.1002/ejic.200600128 |
| Appears in Collections: | College of Science
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