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| Title: | Salt effects on reactivity for substitution reactions of pentacyanoferrate(I1) complexes |
| Authors: | Alshehri, Saad
Burgess, John |
| Keywords: | Iron complexes
Pentacyanoferrdte
Salt effects
Substitution rates |
| تاريخ النشر: | 2003 |
| Publisher: | Old City Publishing |
| Citation: | Inorganic Reaction Mechanisms: 5 ; 59 - 64 |
| Abstract: | Rate constants are reported for ligand replacement in three pentacyanoferrate(III) conmplexes [Fe(CN)5L]3- with L = 4-cyanopyridine, 4,4'-bipyridyl. or 4-t-butyl-pyridine, in a range of aqueous salt solutions. These salts include chlorides and bromides of potassium, lithium, and calcium, and tetra-alkyl-ammonium bromides, at concentrations within the range 0.50 and 2.00 mol dw-3. The observed trends are compared with those for a selection of other inorganic reactions. |
| Description: | Department of Chemistry. College of Science, King Sand University, P.O. Box 2455. Riyadh 1i4$ I, Saudi Arabia |
| URI: | http://hdl.handle.net/123456789/6548 |
| يظهر في المجموعات: | College of Science
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جميع جميع الابحاث محمية بموجب حقوق الطباعة، جميع الحقوق محفوظة.
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