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Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/6548

Title: Salt effects on reactivity for substitution reactions of pentacyanoferrate(I1) complexes
Authors: Alshehri, Saad
Burgess, John
Keywords: Iron complexes
Salt effects
Substitution rates
Issue Date: 2003
Publisher: Old City Publishing
Citation: Inorganic Reaction Mechanisms: 5 ; 59 - 64
Abstract: Rate constants are reported for ligand replacement in three pentacyanoferrate(III) conmplexes [Fe(CN)5L]3- with L = 4-cyanopyridine, 4,4'-bipyridyl. or 4-t-butyl-pyridine, in a range of aqueous salt solutions. These salts include chlorides and bromides of potassium, lithium, and calcium, and tetra-alkyl-ammonium bromides, at concentrations within the range 0.50 and 2.00 mol dw-3. The observed trends are compared with those for a selection of other inorganic reactions.
Description: Department of Chemistry. College of Science, King Sand University, P.O. Box 2455. Riyadh 1i4$ I, Saudi Arabia
URI: http://hdl.handle.net/123456789/6548
Appears in Collections:College of Science

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